Аннотация:Give me four: The synthesis, structure, and reactivity of [GeCl]+ and [SnCl]+ cations bearing a carbodiphosphorane as ancillary ligand are presented. In the Ge compound, simultaneous σ and π donation from the carbodiphosphorane to Ge is observed (see HOMO (left) and HOMO−1 (right); C black, H white, P orange, Cl green, Ge purple (not visible)), whereas only the σ dative component is present in the Sn analogue.
Ключевые слова:Synthesis and characterization of novel inorganic/organometallic compounds, Organometallic Compounds Synthesis and Characterization, Organometallic Complex Synthesis and Catalysis
