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Local Band GapMeasurements by VEELSof Thin Film SolarCells Debora KellerStephan BuechelerPatrick Reinhard2014 год

Local Band Gap Measurements by VEELS of Thin Film Solar Cells
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Аннотация: Abstract This work presents a systematic study that evaluates the feasibility and reliability of local band gap measurements of Cu(In,Ga)Se 2 thin films by valence electron energy-loss spectroscopy (VEELS). The compositional gradients across the Cu(In,Ga)Se 2 layer cause variations in the band gap energy, which are experimentally determined using a monochromated scanning transmission electron microscope (STEM). The results reveal the expected band gap variation across the Cu(In,Ga)Se 2 layer and therefore confirm the feasibility of local band gap measurements of Cu(In,Ga)Se 2 by VEELS. The precision and accuracy of the results are discussed based on the analysis of individual error sources, which leads to the conclusion that the precision of our measurements is most limited by the acquisition reproducibility, if the signal-to-noise ratio of the spectrum is high enough. Furthermore, we simulate the impact of radiation losses on the measured band gap value and propose a thickness-dependent correction. In future work, localized band gap variations will be measured on a more localized length scale to investigate, e.g., the influence of chemical inhomogeneities and dopant accumulations at grain boundaries.
Год издания: 2014
Авторы: Debora Keller, Stephan Buecheler, Patrick Reinhard, Fabian Pianezzi, Darius Pohl, Alexander R. Surrey, Bernd Rellinghaus, Rolf Erni, Ayodhya N. Tiwari
Издательство: Oxford University Press
Источник: Microscopy and Microanalysis
Ключевые слова: Chalcogenide Semiconductor Thin Films, Quantum Dots Synthesis And Properties, Semiconductor materials and interfaces
Другие ссылки: Microscopy and Microanalysis (HTML)
Repository for Publications and Research Data (ETH Zurich) (PDF)
Repository for Publications and Research Data (ETH Zurich) (HTML)
DORA Empa (Swiss Federal Laboratories for Materials Science and Technology (Empa)) (PDF)
DORA Empa (Swiss Federal Laboratories for Materials Science and Technology (Empa)) (HTML)
reroDoc Digital Library (HTML)
PubMed (HTML)