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Zipping and Unzippingof a PaddlewheelMetal–OrganicFramework to EnableTwo‐Step Syntheticand StructuralTransformation P. SmartCharles A. MasonJason R. Loader2013 год

Zipping and Unzipping of a Paddlewheel Metal–Organic Framework to Enable Two‐Step Synthetic and Structural Transformation
статья из журнала

Страница публикацииПубликация в OpenAlex
Аннотация: MOF zipper: Thermal removal of axial pyridine ligands from the non-covalently pillared metal–organic framework [Zn2(camph)2(py)2]⋅2EtOH prompts migration of alternate camphorate ligands to zip Zn centers from adjacent layers into continuous chains within the nonporous material [Zn2(camph)2] (see scheme). Unzipping to generate new pillared, layered MOFs occurs on exposure to new axial ligands.
Год издания: 2013
Авторы: P. Smart, Charles A. Mason, Jason R. Loader, Anthony J. H. M. Meijer, Alastair J. Florence, Kenneth Shankland, Ashleigh J. Fletcher, Stephen P. Thompson, Michela Brunelli, A.H. Hill, Lee Brammer
Издательство: Wiley
Источник: Chemistry - A European Journal
Ключевые слова: Metal-Organic Frameworks: Synthesis and Applications, Magnetism in coordination complexes, X-ray Diffraction in Crystallography
Другие ссылки: Chemistry - A European Journal (HTML)
PubMed (HTML)