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Self-Organized PorousTitanium OxidePrepared in H[sub2]SO[sub 4]/HFElectrolytes Radim BeránekH. HildebrandPatrik Schmuki2003 год

Self-Organized Porous Titanium Oxide Prepared in H[sub 2]SO[sub 4]/HF Electrolytes
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Аннотация: The formation of porous on titanium was investigated in electrolytes containing low concentrations of HF (0.05-0.4 wt %). Under optimized electrolyte conditions and extended polarization, highly ordered porous is obtained that consists of pore arrays with single pore diameter of 140 nm and a pore spacing of 150 nm. During the formation process, significant current oscillations are observed with an amplitude which depends strongly on the HF content of the electrolyte. Electrochemical, scanning electron microscope and X-ray photoelectron spectroscopy investigations show that the porous layer forms under a competition of formation and oxide dissolution up to a limiting thickness of and that the time scale for complete self-ordering for the investigated systems is in the order of several hours. © 2003 The Electrochemical Society. All rights reserved.
Год издания: 2003
Авторы: Radim Beránek, H. Hildebrand, Patrik Schmuki
Издательство: Electrochemical Society
Источник: Electrochemical and Solid-State Letters
Ключевые слова: Anodic Oxide Films and Nanostructures, Electrocatalysts for Energy Conversion, Nanoporous metals and alloys