Synthesis and Structural Features of the Nickel(II) Complex with Pincer 1,3-bis((diphenyl)phosphinoxy)Phenyl and Terminal Trifluoroacetate Ligands : научное издание
Библиографическое описание:Synthesis and Structural Features of the Nickel(II) Complex with Pincer 1,3-bis((diphenyl)phosphinoxy)Phenyl and Terminal Trifluoroacetate Ligands : научное издание / O. S. Chudin, D. S. Volkova, A. Yu. Fedorov [et al.]. - Текст : непосредственный // Journal of Structural Chemistry. - 2026. - Т.67, №5. - P. 1099-1108. - The work was supported by the Ministry of Science and Higher Education of the Russian Federation within basic budget financing projects for the Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences (project FWES-2026-0011) And the State Assignment for the Multi-Access Center SKIF of the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (project FWUR-2024-0040). - ISSN 0022-4766. - ISSN 1573-8779, DOI 10.1134/S0022476626050136.
Аннотация:The synthesis procedure is developed for the pincer 1,3-bis((diphenyl)phosphinoxy)phenyl complexa of nickel [{C<sub>6</sub>H<sub>3</sub>-1,3-(OPPh<sub>2</sub>)<sub>2</sub>}NiI] (<b>1</b>) by the direct interaction of 1,3-bis((diphenyl)phosphinoxy)benzene with [(CH<sub>3</sub>CN)<sub>3</sub>NiI<sub>2</sub>]. By the reaction of complex <b>1</b> with silver trifluoroacetate, new complex [{C<sub>6</sub>H<sub>3</sub>-1,3-(OPPh<sub>2</sub>)<sub>2</sub>}NiOC(O)CF<sub>3</sub>] (<b>2</b>) is obtained with a quantitative yield. The compounds are characterized by <sup>1</sup>H, <sup>13</sup>C{<sup>1</sup>H}, <sup>31</sup>P{<sup>1</sup>H}, and <sup>19</sup>F NMR spectroscopy. The structure of complex <b>2</b> is determined by single crystal X-ray diffraction.<img src="/get_item_image.asp?id=91554667&img=10947_2026_3288_Figa_HTML.png" class="img_big">
Держатель оригинала документа:Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Multi-Access Center SKIF, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Siberian Federal University
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