High-vacuum carbosilicothermic reduction of manganese in thin films : научное издание

Andryushchenko Tatyana A.; Lyaschenko Sergey A.; Nemtsev Ivan V.; Lukyanenko Anna V.; Tomashevich Yevgeny V.; Varnakov Sergey N.; Ovchinnikov Sergei G.

Дополнительные ссылки: eLibrary

База данных: Каталог библиотеки СФУ

Библиографическое описание: High-vacuum carbosilicothermic reduction of manganese in thin films : научное издание / Tatyana A. Andryushchenko, Sergey A. Lyaschenko, Ivan V. Nemtsev [et al.]. - Текст : непосредственный // Vacuum. - 2025. - Т. 239, № . - P. 114398. - The research was carried out within the state assignment of Kirensky Institute of Physics. The authors are grateful to Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” for obtaining SEM, EDX and XPS data. The authors also thank Felix N. Tomilin from the Kirensky Institute of Physics for valuable comments regarding the thermodynamic analysis of the systems studied in this work. - ISSN 0042-207X, DOI 10.1016/j.vacuum.2025.114398.

Аннотация: High-vacuum carbosilicothermic reduction of MnOx thin films on Si(100) substrates was investigated in the temperature range of 200–700 °C using in-situ Auger electron spectroscopy along with mass spectroscopy and ex-situ X-ray photoelectron spectroscopy. Carbothermic reduction of manganese, accompanied by the CO evolution, occurs over the entire temperature range. When heated above 500 °C, silicothermic reduction and formation of manganese silicides are observed. The efficiency of carbothermic reduction of Mn in thin films turned out to be higher at C:Mn = 1:10 than at C:Mn = 1:5. Carbon in the samples is assumed to be present in two forms: as amorphous carbon in a mixture with oxygen and manganese, and as individual, larger particles with a graphite structure. The particle size depends on the power of the magnetron source and influences the carbon coalescence activity, which competes with the carbothermic reduction process. The efficiency of silicothermic reduction on the film surface depends on the initial carbon concentration.

Год издания: 2025

Авторы: Andryushchenko Tatyana A. , Lyaschenko Sergey A. , Nemtsev Ivan V. , Lukyanenko Anna V. , Tomashevich Yevgeny V. , Varnakov Sergey N. , Ovchinnikov Sergei G.

Издательство: Elsevier Science Publishing Company, Inc.

Источник: Vacuum

Выпуск: Т. 239

Номера страниц: 114398

Держатель оригинала документа: Federal Research Center KSC SB RAS, Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS

Количество экземпляров:

Твёрдая копия издания отсутствует в фонде библиотеки

Показать дополнительные сведения

Auger Electron Spectroscopy of Thin Cr2GeC Films : научное издание

Andryushchenko T. A. и др.
2023 год

Kinetics of intermetallic phase formation in multilayer Al/Pt thin films : научное издание

Moiseenko Evgeny T. и др.
2025 год

Structure, electronic and optical properties of (Cr1-xMnx)2GeC MAX phase: DFT calculations and… : научное издание

Andryushchenko Tatyana A. и др.
2025 год

Features of the Course of the Solid-State Reactions in a Sn/Fe/Cu Trilayer Film System : научное издание

Balashov Yu.Yu. и др.
2024 год

Thin Magnetic Film Magnetometer : статья из журнала

Burmitskikh Anton V. и др.
2025 год

Buffer Layer Effect on the Structure, Morphology, and Magnetic Properties of Mn5Ge3 Films… : статья из журнала

Rautskii M.V. и др.
2024 год

Selective synthesis of higher manganese silicides: a new Mn17Si30 phase, its electronic,… : сборник научных трудов

Tarasov Ivan A. и др.
2018 год

Numerical calculation of high frequency magnetic susceptibility in thin nanocrystalline magnetic films : научное издание

Izotov A.V и др.
2019 год

Halogen-substituted zinc(II) phthalocyanines: Spectral properties and structure of thin films : статья из журнала

Klyamer D. и др.
2022 год

In Situ Electron Diffraction and Resistivity Characterization of Solid State Reaction Process in Cu… : научное издание

Moiseenko Evgeny T. и др.
2020 год

Chemiresistive NH3 and H2S sensors based on thin films of vitamin B12 derivatives : научное издание

Klyamer D. и др.
2024 год

Sublayer-Enhanced Growth of Highly Ordered Mn5Ge3 Thin Film on Si(111) : научное издание

Yakovlev Ivan и др.
2022 год

CHANGE IN MAGNETORESISTANCE IN MANGANESE CHALCOGENIDES MnSe1-XTeX FROM BULK TO THIN-FILM SAMPLES : научное издание

Aplesnin S.S. и др.
2020 год

Growth Process, Structure and Electronic Properties of Cr2GeC and Cr2-xMnxGeC Thin Films Prepared… : научное издание

Tarasov Anton S. и др.
2023 год

Numerical simulation of magnetic microstructure in nanocrystalline thin films with the random… : статья из журнала

Belyaev Boris A. и др.
2017 год

Formation of Cu6Sn5 intermetallic in Cu/Sn thin films : статья из журнала

Bykova L. E. и др.
2022 год

Библиотечно-издательский комплекс СФУ

High-vacuum carbosilicothermic reduction of manganese in thin films : научное издание
статья из журнала

Похожие публикации