1. Главная
  2. Ресурсы
  3. Библиотечный поиск
Temperature/Component-DependentLuminescence inLead-Free HybridMetal Halides forTemperature SensorandAnti-Counterfeiting Zhou GuojunWang YantingMao Yilin2024 год

Temperature/Component-Dependent Luminescence in Lead-Free Hybrid Metal Halides for Temperature Sensor and Anti-Counterfeiting : научное издание
статья из журнала

Дополнительные ссылки: eLibrary
База данных: Каталог библиотеки СФУ
Библиографическое описание: Temperature/Component-Dependent Luminescence in Lead-Free Hybrid Metal Halides for Temperature Sensor and Anti-Counterfeiting : научное издание / G. G. Zhou [et al.]. - Текст : непосредственный // Advanced Functional Materials. - 2024. - № . - ISSN 1616-301X. - ISSN 1616-3028, DOI 10.1002/adfm.202401860.
Аннотация: <jats:title>Abstract</jats:title><jats:p>Hybrid metal halides (HMHs) have emerged as a promising platform for optically functional crystalline materials, but it is extremely challenging to thoroughly elucidate the electron transition coupled to additional ligand emission. Herein, to discover sequences of lead-free HMHs with distinct optically active metal cations are aimed, that is, Sb<jats:sup>3+</jats:sup> (5s<jats:sup>2</jats:sup>) with the lone-pair electron configuration and In<jats:sup>3+</jats:sup> (4d<jats:sup>10</jats:sup>) with the fully-filled electron configuration. (Me<jats:sub>2</jats:sub>NH<jats:sub>2</jats:sub>)<jats:sub>4</jats:sub><jats:italic>M</jats:italic>Cl<jats:sub>6</jats:sub>·Cl (Me = −CH<jats:sub>3</jats:sub>, <jats:italic>M</jats:italic> = Sb, In) exhibits the superior temperature/component-dependent luminescence behaviors resulting from the competition transition between triplet-states (T<jats:sub>n</jats:sub>-S<jats:sub>0</jats:sub>) self-trapped excitons (STEs) of inorganic units and singlet-state (S<jats:sub>1</jats:sub>-S<jats:sub>0</jats:sub>) of organic cations, which is manipulated by the optical activity levels of [SbCl<jats:sub>6</jats:sub>]<jats:sup>3−</jats:sup> and [InCl<jats:sub>6</jats:sub>]<jats:sup>3−</jats:sup>. The bonding differences between Sb<jats:sup>3+</jats:sup>/In<jats:sup>3+</jats:sup> and Cl<jats:sup>−</jats:sup> in terms of electronic excitation and hybridization are emphasized, and the different electron-transition mechanisms are established according to the PL spectra at the extreme temperature of 5 to 305 K and theoretical calculations. By fine-tuning the B-site Sb<jats:sup>3+</jats:sup>/In<jats:sup>3+</jats:sup> alloying, the photoluminescence quantum yield (PLQY = 81.5%) and stability are optimized at 20% alloying of Sb<jats:sup>3+</jats:sup>. This research sheds light on the rules governing PL behaviors of HMHs, as well as exploring the optical-functional application of aviation temperature sensors and access-control systems.</jats:p>
Год издания: 2024
Авторы: Zhou Guojun , Wang Yanting , Mao Yilin , Guo Caihong , Zhang Jian , Molokeev Maxim S. , Xia Zhiguo , Zhang Xian-Ming
Издательство: Wiley Interscience, Weinheim
Источник: Advanced Functional Materials
Держатель оригинала документа: College of Chemistry & Chemical Engineering Key Laboratory of Interface Science and Engineering in Advanced Material Ministry of Education Taiyuan University of Technology Taiyuan Shanxi 030024 P. R. China, International Research Center of Spectroscopy and Quantum Chemistry-IRC SQC Siberian Federal University Krasnoyarsk 660041 Russia, Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education) School of Chemistry and Material Science Shanxi Normal University Taiyuan 030031 P. R. China, Laboratory of Crystal Physics Kirensky Institute of Physics Federal Research Center KSC SB RAS Krasnoyarsk 660036 Russia, State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices School of Physics and Optoelectronics South China University of Technology Guangzhou Guangdong 510641 P. R. China
Количество экземпляров:
Твёрдая копия издания отсутствует в фонде библиотеки

Похожие публикации

DynamicPhosphorescence/Fluorescence Switching inHybrid Metal HalidesToward Time-ResolvedMulti-Level Anti… Zhou GuojunMao YilinZhang Jian2024 год

Dynamic Phosphorescence/Fluorescence Switching in Hybrid Metal Halides Toward Time-Resolved Multi… : статья из журнала

  • Zhou Guojun и др.
  • 2024 год
Solvent PolarityTriggered RapidlyReversibleQuadruple-ModeLuminescenceAdjustment in 0DHybrid AntimonyHalides Liao HanruiSun JinxuanLi Wei2025 год

Solvent Polarity Triggered Rapidly Reversible Quadruple-Mode Luminescence Adjustment in 0D Hybrid… : научное издание

  • Liao Hanrui и др.
  • 2025 год
Solvent PolarityTriggered RapidlyReversibleQuadruple-ModeLuminescenceAdjustment in 0DHybrid AntimonyHalides Liao HanruiSun JinxuanLi Wei2025 год

Solvent Polarity Triggered Rapidly Reversible Quadruple-Mode Luminescence Adjustment in 0D Hybrid… : научное издание

  • Liao Hanrui и др.
  • 2025 год
Lead-Free HybridMetal Halides with aGreen-Emissive[MnBr4] Unit as aSelective Turn-OnFluorescent Sensorfor Acetone Li MingzeZhou JunMolokeev Maxim S.2019 год

Lead-Free Hybrid Metal Halides with a Green-Emissive [MnBr4] Unit as a Selective Turn-On… : статья из журнала

  • Li Mingze и др.
  • 2019 год
Luminescenceenhancement effectsof CaSr2‒Nb2O7:Er3+,Tm3+phosphors fortemperature sensingandanti-counterfeiting… Chen WenchaoGao HuaboMolokeev Maxim S.2024 год

Luminescence enhancement effects of Ca Sr2‒Nb2O7:Er3+,Tm3+ phosphors for temperature sensing and… : научное издание

  • Chen Wenchao и др.
  • 2024 год
Near-unity PLQY andhigh anti-thermalquenching redluminescence fromone-dimensionalhybrid manganesechloride for… Su BinbinMolokeev Maxim S.Chen Ran2024 год

Near-unity PLQY and high anti-thermal quenching red luminescence from one-dimensional hybrid… : статья из журнала

  • Su Binbin и др.
  • 2024 год
Chemical GroupSubstitution EnablesHighly EfficientMn4+Luminescence inHeterovalent Systems Ming HongZhao YifeiZhou Yayun2023 год

Chemical Group Substitution Enables Highly Efficient Mn4+Luminescence in Heterovalent Systems : статья из журнала

  • Ming Hong и др.
  • 2023 год
In SituCrystallization ofCopper(I)-BasedHybrid HalidesAssisted byCarboxymethylcellulose Sodium for aLarge-Area… Tang BaolingJin JianceHan Kai2025 год

In Situ Crystallization of Copper(I)-Based Hybrid Halides Assisted by Carboxymethylcellulose Sodium… : научное издание

  • Tang Baoling и др.
  • 2025 год

Показать ещё

Optical ThermometerBased on EfficientNear-InfraredDual-Emission of Cr3+and Ni2+ inMagnetoplumbiteStructure Zhang QianqianLi GuogangLi Guangzhi2024 год

Optical Thermometer Based on Efficient Near-Infrared Dual-Emission of Cr3+ and Ni2+ in… : научное издание

  • Zhang Qianqian и др.
  • 2024 год
Efficient andThermally StableCr3+-Doped PhosphorAchieved by CationSubstitution: PlantLighting Application Dai XiangyiZou XikunWei Mingkai2024 год

Efficient and Thermally Stable Cr3+-Doped Phosphor Achieved by Cation Substitution: Plant… : статья из журнала

  • Dai Xiangyi и др.
  • 2024 год
Highly EfficientMn4+-DopedRed-EmittingOxyfluorides withExcellent WaterResistance TowardFlexible… Liu MinMing HongPan Xixiang2025 год

Highly Efficient Mn4+-Doped Red-Emitting Oxyfluorides with Excellent Water Resistance Toward… : научное издание

  • Liu Min и др.
  • 2025 год
Lossless Phase ChangeMaterials forAdjustable TammPlasmon Polaritons inthe Near-Infrared Ye Ming-JyunBikbaev Rashid G.Pankin Pavel S.2025 год

Lossless Phase Change Materials for Adjustable Tamm Plasmon Polaritons in the Near-Infrared : научное издание

  • Ye Ming-Jyun и др.
  • 2025 год
Unveiling theuncommonblue-excitablebroadband yellowemission fromself-trapped excitonsin azero-dimensional… Mao YiLinZhang JianRen Qiqiong2022 год

Unveiling the uncommon blue-excitable broadband yellow emission from self-trapped excitons in a… : научное издание

  • Mao YiLin и др.
  • 2022 год
Effects ofIsomorphousSubstitution onPhotophysical andMagnetic Propertiesof Complexes [Ln 1- xDy x (MeDPQ) 2… Zhernakov Maksim A.Denisenko Yuriy G.Batulin Ruslan G.2025 год

Effects of Isomorphous Substitution on Photophysical and Magnetic Properties of Complexes [Ln 1- x… : научное издание

  • Zhernakov Maksim A. и др.
  • 2025 год
LixAg1–xGaSe2:Interplay BetweenLithium and Silver inMid-InfraredNonlinear OpticalChalcogenides Isaenko L.Dong LinfengKurus A.2022 год

LixAg1–xGaSe2: Interplay Between Lithium and Silver in Mid-Infrared Nonlinear Optical Chalcogenides : научное издание

  • Isaenko L. и др.
  • 2022 год
Ultra-Wide Vis–NIRMg2Al4Si5O18:Eu2+,Cr3+ Phosphor ContainingUnusual NIRLuminescence Inducedby Cr3+ Occupying… Zou XikunZhang HaoranLi Wei2022 год

Ultra-Wide Vis–NIR Mg2Al4Si5O18:Eu2+,Cr3+ Phosphor Containing Unusual NIR Luminescence Induced by… : научное издание

  • Zou Xikun и др.
  • 2022 год