Библиографическое описание:Synthesis and Sorption Properties of Microsphere Zeolite Materials Based on Coal Fly Ash Cenospheres with Respect to Cs+ and Sr2+ : научное издание / E. A. Kutikhina [et al.]. - Текст : непосредственный // Glass Physics and Chemistry. - 2023. - Т.49, №2. - P. 167-176. - ISSN 1087-6596. - ISSN 1608-313X, DOI 10.1134/S1087659622601071.
Аннотация:The effect of the hydrothermal synthesis conditions (temperature, duration, mixing), composition, and presynthetic processing of narrow fractions of cenospheres of fly ash, which act as a template and source of Si and Al, on the production of microspherical zeolite materials of the given structural type in the Na2O–H2O–(SiO2–Al2O3)glass of two molar compositions is studied. The synthesis products are characterized by XRD, SEM-EDS, and low-temperature nitrogen adsorption, and their sorption properties in relation to Cs+ and Sr2+ are studied. The factors contributing to the predominant formation of NaX zeolite of the faujasite structural type are revealed. It is established that zeolite products based on cenospheres with a glass phase content of about 95 wt % demonstrate the highest sorption parameters, including the maximum capacity for Cs+ and Sr2+ of up to 250 and 180 mg/g, distribution coefficient of about 104 and 106 mL/g, and degree of extraction of 99.1 and 99.9%, respectively.
Издательство:Pleiades Publishing, Ltd. (Плеадес Паблишинг, Лтд), Санкт-Петербург
Источник:Glass Physics and Chemistry
Выпуск:Т.49, №2
Номера страниц:167-176
Держатель оригинала документа:Institute of Chemistry and Chemical Technology, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Siberian Federal University
Количество экземпляров:
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