Constructing slow-release formulations of herbicide metribuzin using its co-extrusion with biodegradable polyester poly-ε-caprolactone : научное издание
Библиографическое описание:Constructing slow-release formulations of herbicide metribuzin using its co-extrusion with biodegradable polyester poly-ε-caprolactone : научное издание / A. N. Boyandin, E. A. Kazantseva. - Текст : непосредственный // Journal of Environmental Science and Health. Part B: Pesticides, Food Contaminants, and Agricultural Wastes. - 2021. - № . - ISSN 0360-1234. - ISSN 1532-4109, DOI 10.1080/03601234.2021.1911206.
Аннотация:Different technologies to prepare long term pesticide forms include polymer coating, preparing composites and encapsulating pesticides in nanoparticles. A simple and low-cost method was proposed to obtain slow-release formulations by co-extrusion of a pesticide with a biodegradable polymer at a temperature above the melting points of both components. A herbicide metribuzin and low-melting polyester poly-ε-caprolactone were chosen for this work. Formulations containing 10%, 20%, and 40% herbicide were prepared. During 7 days of their exposition in water, it was released from 81% to 96% of initially loaded metribuzin; the highest release was detected for 40%-loaded forms. Biodegradation of the constructs and pesticide release were further studied in the model soil. Degradation rates of the specimens increased with an increase in pesticide content, from 9% to 20% over 14 weeks for the 10%/20%-loaded and the 40%-loaded specimens, respectively. The release of metribuzin reached, respectively, 37–38% and 55%. The herbicide content in soil was lower due to its partial degradation in soil; it reached 23–25% and 33%, respectively, from initially loaded into the polymer matrix. Release kinetics of metribuzin in water as in soil best fitted the First-order model. The used approach is promising for obtaining long-term release formulations for soil applications.
Источник:Journal of Environmental Science and Health. Part B: Pesticides, Food Contaminants, and Agricultural Wastes
Держатель оригинала документа:Institute of Biophysics of Siberian Branch of Russian Academy of Sciences,Federal Research Center “Krasnoyarsk Science Center SB RAS”, Siberian Federal University
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