Synthesis of heterometallic metal–organic frameworks and their performance as electrocatalyst for CO 2 reduction

…, G Beobide, O Castillo, A Irabien, S Pérez-Yáñez - RSC …, 2018 - pubs.rsc.org
Herein we report the solventless synthesis and doping of the benchmark HKUST-1(Cu) as a
facile route to afford heterometallic metal–organic frameworks (MOFs) having proficient …

Metal–carboxylato–nucleobase systems: From supramolecular assemblies to 3D porous materials

…, O Castillo, J Cepeda, A Luque, S Pérez-Yáñez… - Coordination Chemistry …, 2013 - Elsevier
A complete overview of the preparation of metal–carboxylato–nucleobase architectures that
range from supramolecular assemblies to 3D porous materials is reported. The basic …

Scandium/alkaline metal–organic frameworks: adsorptive properties and ionic conductivity

J Cepeda, S Pérez-Yáñez, G Beobide… - Chemistry of …, 2016 - ACS Publications
Several synthetic approaches have been employed to obtain novel {[ScM(μ 4 -pmdc) 2 (H 2
O) 2 ]·solv} n [EHU1(Sc,M)] (where M = Li, Na; pmdc = pyrimidine-4,6-dicarboxylate; solv = …

[HTML][HTML] Copper (II)-porphyrin functionalized titanium (IV) metal-organic aerogels for the visible-light driven conversion of CO2 to alcohols

…, G Beobide, O Castillo, A Luque, S Pérez-Yánez - Materials Today …, 2023 - Elsevier
This manuscript covers the synthesis and characterization of a series of titanium based
metal-organic aerogels (MOAs) functionalized with copper(II)-metalated porphyrins for their …

Copper(II) invigorated EHU-30 for continuous electroreduction of CO2 into value-added chemicals

…, ASJ Méndez, AE Platero-Prats, S Pérez-Yáñez - Scientific reports, 2022 - nature.com
The doping of zirconium based EHU-30 and EHU-30-NH 2 metal–organic frameworks with
copper(II) yielded a homogeneous distribution of the dopant with a copper/zirconium ratio of …

[HTML][HTML] Metal-organic aerogels based on titanium (IV) for visible-light conducted CO2 photoreduction to alcohols

…, G Beobide, O Castillo, S Pérez-Yáñez - Materials Today …, 2022 - Elsevier
Metal-organic frameworks (MOFs) imply an appealing source of photocatalysts as they combine
porosity with tailorable electronic properties and surface chemistry. Herein, we report a …

A straightforward route to obtain zirconium based metal-organic gels

…, P Castaño, O Castillo, A Luque, S Pérez-Yáñez - Microporous and …, 2019 - Elsevier
Zirconium based metal-organic gels are obtained through a rapid method at room temperature,
employing green solvents, in which the role of water is important. These porous materials…

Paddle-Wheel Shaped Copper (II)-Adenine Discrete Entities As Supramolecular Building Blocks To Afford Porous Supramolecular Metal–Organic Frameworks …

J Thomas-Gipson, G Beobide, O Castillo… - Crystal growth & …, 2014 - ACS Publications
The present work assesses the ability of [Cu 2 (μ-adenine) 4 (X) 2 ] 2+ and [Cu 2 (μ-adenine)
2 (μ-X) 2 (X) 2 ] (X: Cl – or Br – ) metal-nucleobase dinuclear entities to build up …

Open-framework copper adeninate compounds with three-dimensional microchannels tailored by aliphatic monocarboxylic acids

S Pérez-Yánez, G Beobide, O Castillo… - Inorganic …, 2011 - ACS Publications
A series of isostructural copper(II) coordination polymers containing the nucleobase adenine
and different monocarboxylic acids as bridging ligands, [Cu 2 (μ 3 -ade) 2 (μ 2 -OOC(CH 2 ) …

Chemically Resistant, Shapeable, and Conducting Metal‐Organic Gels and Aerogels Built from Dithiooxamidato Ligand

…, A Luque, P Ocón, S PérezYáñez - Advanced Functional …, 2017 - Wiley Online Library
Metal‐organic gels (MOGs) appear as a blooming alternative to well‐known metal‐organic
frameworks (MOFs). Porosity of MOGs has a microstructural origin and not strictly crystalline …