Crystalline solids with extended non-interpenetrating three-dimensional crystal structures
were synthesized that support well-defined pores with internal diameters of up to 48 angstroms…

The concept and occurrence of isoreticular (same topology) series of metal–organic
frameworks (MOFs) is reviewed. We describe the preparation, characterization, and crystal …

Metal–organic framework-177 (MOF-177) is one of the most porous materials whose structure
is composed of octahedral Zn 4 O(−COO) 6 and triangular 1,3,5-benzenetribenzoate (BTB…

Separation of acetylene from carbon dioxide and ethylene is challenging in view of their
similar sizes and physical properties. Metal–organic frameworks (MOFs) in general are strong …

MIL-101 and MIL-101–NH2 were partially modified to incorporate various functional groups
that are capable of forming hydrogen bonds with water. Specifically, MIL-101–NH2 was …

The functionalization of UiO-67 with–NH2 groups enhances CO2 and CH4 adsorption at 1
bar and 298 K and positively influences the framework's interaction with water as evidenced …

Three functionalized metal–organic frameworks (MOFs), MOF-205-NH2, MOF-205-NO2,
and MOF-205-OBn, formulated as Zn4O(BTB)4/3(L), where BTB is benzene-1,3,5-tribenzoate …

A new type of click reaction, sulfur(VI) fluoride exchange (SuFEx), has been utilized to
prepare five postsynthetically modified UiO-67 series metal–organic frameworks (MOFs). The …

A two-dimensional metal–organic framework (MOF) containing both Zn(II) and Ca(II) centres
and a three-dimensional MOF containing only Ca(II) centres have the largest surface areas (…

A methyl-modified metal–organic framework (m-TiBDC) shows significantly enhanced
hydrostability than unmodified TiBDC, and thus can maintain almost intact CO2 gas …