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New triple molybdate K5ScHf(MoO4)6: Synthesis, properties, structure and phase equilibria in the M2MoO4–Sc2(MoO4)3–Hf(MoO4)2 (M = Li, K) systems
(2020-03)
New triple molybdate K5ScHf(MoO4)6: Synthesis, Properties, Structure and
Phase Equilibria in the M2MoO4–Sc2(MoO4)3–Hf(MoO4)2 (M = Li, K) systems
Victoria G. Grossman
a
, Jibzema G. Bazarova
a
, Maksim S. Molokeev
b,c
,
Bair G. Bazarov
a
a
Baikal...
, Krasnoyarsk 660036, Russia c Siberian Federal University, 82 Svobodniy Av., Krasnoyarsk 660041, Russia E-mail address:grossmanv@mail.ru ABSTRACT Subsolidus phase relations in the M2MoO4–Sc2(MoO4)3–Hf(MoO4)2 (M = Li, K) systems have been studied...
, Krasnoyarsk 660036, Russia c Siberian Federal University, 82 Svobodniy Av., Krasnoyarsk 660041, Russia E-mail address:grossmanv@mail.ru ABSTRACT Subsolidus phase relations in the M2MoO4–Sc2(MoO4)3–Hf(MoO4)2 (M = Li, K) systems have been studied...
Влияние гетерофазного допирования на транспортные свойства димолибдата лантана
(Сибирский федеральный университет. Siberian Federal University, 2019-06)
)Mo(2)O(9). The effect of temperature and oxygen partial pressure in the
gas phase on conductivity of the obtained composite {0.85La2Mo2O9–0.15La2Mo3O12} was studied.
Introduction of 15 mol. % an inert low-conductive additional phase La(2)Mo(3)O(12...
) results in an increase in conductivity of the matrix phase by nearly 1 orders of magnitude. It is associated with appearance of a composite effect. However, there is no suppression of the α-La(2)Mo(2)O(9)↔β-La(2) Mo(2)O(9) phase transition. It is shown...
) results in an increase in conductivity of the matrix phase by nearly 1 orders of magnitude. It is associated with appearance of a composite effect. However, there is no suppression of the α-La(2)Mo(2)O(9)↔β-La(2) Mo(2)O(9) phase transition. It is shown...
Thallium ionic conductivity of new thallium indium hafnium molybdate ceramics
(2020-08)
., Krasnoyarsk 660041, Russia
E-mail address:grossmanv@mail.ru
ABSTRACT
In the process of studying the system Tl2MoO4–In2(MoO4)3–Hf(MoO4)2, a new thallium indium hafnium
molybdate was found. The crystal structure of the molybdate Tl5InHf(MoO4...
)6 was determined in the centrosymmetric space group R c (a = 10.63893 (5) Å, c = 38.1447(3) Å; V = 3739.04 (4) Å3, Z = 6). The structure is a framework consisting and contains alternating mixed (Hf,In)O6 octahedra connected by MoO4 tetrahedra. The structure is a...
)6 was determined in the centrosymmetric space group R c (a = 10.63893 (5) Å, c = 38.1447(3) Å; V = 3739.04 (4) Å3, Z = 6). The structure is a framework consisting and contains alternating mixed (Hf,In)O6 octahedra connected by MoO4 tetrahedra. The structure is a...
ВЕДУЩИЙ СТРУКТУРНЫЙ ПАРАМЕТР И ПРОГНОЗ СИНТЕЗА ПЕРСПЕКТИВНЫХ МАТЕРИАЛОВ ИЗ РЯДА ДВОЙНЫХ МОЛИБДАТОВ АLn (MoO4)2. ОПРЕДЕЛЕНИЕ СТРУКТУРЫ ? – ФАЗЫ RbSm(MoO4)2
(Сибирский федеральный университет, 2014)
ПАРАМЕТР И ПРОГНОЗ СИНТЕЗА
ПЕРСПЕКТИВНЫХ МАТЕРИАЛОВ ИЗ РЯДА ДВОЙНЫХ МОЛИБДАТОВ
АLn (MoO4)2. ОПРЕДЕЛЕНИЕ СТРУКТУРЫ β – ФАЗЫ RbSm(MoO4)2
Тачеева Н.Н.
научные руководители д-р.физ.-мат. наук, проф. Мисюль С.В., канд.физ.-мат.наук,
ст.науч. сотр...
. Молокеев М.С. Институт инженерной физики и радиоэлектроники Сибирского Федерального Университета Рассмотрены структуры двойных молибдатов с общей формулой ALn(MoO4)2 (А = Li - Cs, Cu, Ag; Ln = La - Lu). Показано, что отношение радиусов RLn/RA ионов...
. Молокеев М.С. Институт инженерной физики и радиоэлектроники Сибирского Федерального Университета Рассмотрены структуры двойных молибдатов с общей формулой ALn(MoO4)2 (А = Li - Cs, Cu, Ag; Ln = La - Lu). Показано, что отношение радиусов RLn/RA ионов...
SYNTHESIS AND MICROSTRUCTURAL PROPERTIES OF CUBIC CsMnMoO3F3 OXYFLUORIDE
(Сибирский федеральный университет, 2012-10-08)
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SYNTHESIS...
AND MICROSTRUCTURAL PROPERTIES OF CUBIC CsMnMoO3F3 OXYFLUORIDE 1T.A. Gavrilova, 2N.M. Laptash, 3V.V. Atuchin, 4M.S. Molokeev 1Laboratory of Nanodiagnostics and Nanolithography, A.V.Rzhanov Institute of Semiconductor Physics, SB RAS, Novosibirsk 90, 630090...
AND MICROSTRUCTURAL PROPERTIES OF CUBIC CsMnMoO3F3 OXYFLUORIDE 1T.A. Gavrilova, 2N.M. Laptash, 3V.V. Atuchin, 4M.S. Molokeev 1Laboratory of Nanodiagnostics and Nanolithography, A.V.Rzhanov Institute of Semiconductor Physics, SB RAS, Novosibirsk 90, 630090...
[Pd(NH3)4]MoO4 – ПРЕДШЕСТВЕННИК КАТАЛИЗАТОРОВ, СОДЕРЖАЩИХ ПАЛЛАДИЙ И МОЛИБДЕН.
(Сибирский федеральный университет, 2013)
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[Pd(NH3)4]MoO4– ПРЕДШЕСТВЕННИК КАТАЛИЗАТОРОВ, СОДЕРЖАЩИХ
ПАЛЛАДИЙ И МОЛИБДЕН.
1,2ГубановА.И., 1,2Семитут Е.Ю., 2,3Потемкин Д.И.
1Федеральное государственное бюджетное учреждение науки Институт неорганиче-
ской химии им. А.В. Николаева...
современном материаловедении. Одним из перспективных методов является разложение двойных комплексных солей (ДКС). Со- единение [Pd(NH3)4]MoO4, хоть и не относится к классу двойных комплексных солей, так как анион MoO4 2- не является координационным...
современном материаловедении. Одним из перспективных методов является разложение двойных комплексных солей (ДКС). Со- единение [Pd(NH3)4]MoO4, хоть и не относится к классу двойных комплексных солей, так как анион MoO4 2- не является координационным...
Exploration of structural, vibrational and spectroscopic properties of self-activated orthorhombic double molybdate RbEu(MoO 4 ) 2 with isolated MoO 4 units
(2019-05)
RbEu(MoO 4 ) 2 is synthesized by the two-step solid state reaction method. The crystal structure of RbEu(MoO 4 ) 2 is defined by Rietveld analysis in space group Pbcn with cell parameters a = 5.13502(5), b = 18.8581(2) and c = 8.12849(7) Å, V = 787...
SYNTHESIS, MORPHOLOGY AND STRUCTURAL PROPERTIES OF MICROCRYSTALLINE RbSm(MoO4)2
(Сибирский федеральный университет, 2012-10-08)
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SYNTHESIS...
, MORPHOLOGY AND STRUCTURAL PROPERTIES OF MICROCRYSTALLINE RbSm(MoO4)2 1T.A. Gavrilova, 2V.V. Atuchin, 3O.D. Chimitova, 4M.S. Molokeev, 3B.G. Bazarov, 3Zh.G. Bazarova 1Laboratory of Nanodiagnostics and Nanolithography, Institute of Semiconductor...
, MORPHOLOGY AND STRUCTURAL PROPERTIES OF MICROCRYSTALLINE RbSm(MoO4)2 1T.A. Gavrilova, 2V.V. Atuchin, 3O.D. Chimitova, 4M.S. Molokeev, 3B.G. Bazarov, 3Zh.G. Bazarova 1Laboratory of Nanodiagnostics and Nanolithography, Institute of Semiconductor...
Structural and spectroscopic properties of self-activated monoclinic molybdate BaSm2(MoO4)4
(2017-12)
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Corresponding author: V.V. Atuchin Institute of Semiconductor Physics, Novosibirsk 630090, Russia Fax: +7 (383) 3332771 E-mail: atuchin@isp.nsc.ru Structural and spectroscopic properties of self-activated monoclinic molybdate BaSm2(MoO4)4 V...
Corresponding author: V.V. Atuchin Institute of Semiconductor Physics, Novosibirsk 630090, Russia Fax: +7 (383) 3332771 E-mail: atuchin@isp.nsc.ru Structural and spectroscopic properties of self-activated monoclinic molybdate BaSm2(MoO4)4 V...
Microwave sol-gel synthesis of microcrystalline CaGd2(MoO4)4:Er3+/Yb3+ phosphors and their upconversion photoluminescence properties
(2015-10)
CaGd2(MoO4)4:Er3+/Yb3+ phosphors with the doping concentrations of Er3+ and Yb3+ (x = Er3+ + Yb3+, Er3+ = 0.05, 0.1, 0.2, and Yb3+ = 0.2, 0.45) have been successfully synthesized by the microwave sol–gel method, and the crystal structure refinement...