Sodium Borohydride, Its Hydrolysis and its Use as a Reducing Agent and in the Generation of Hydrogen1

HI Schlesinger, HC Brown, AE Finholt… - Journal of the …, 1953 - ACS Publications
Sodium borohydride reacts slowly with water ultimately to liberate 4 moles of hydrogen per
mole of the compound at room temperature, or 2.4 1. per gram. The reaction is greatly …

Forty years of hydride reductions

HC Brown, S Krishnamurthy - Tetrahedron, 1979 - Elsevier
Forty years ago, it was observed that diborane, a hydride, reduces aldehydes and ketones
with exceptional ease even at 0. Since then various hydride reagents have evolved for the …

[BOOK][B] Boranes in organic chemistry

HC Brown - 2019 - books.google.com
The leading researcher in the uses of boranes in organic synthesis here reviews his work
over the past thirty-five years, covering such areas as steric strains, the nonclassical ion …

Electrophilic substituent constants

HC Brown, Y Okamoto - Journal of the American Chemical …, 1958 - ACS Publications
An excellent linear relationship is observed between log (k/kn) for sixteen meta substituted¿-cumyl
chlorides and the Hammett meta substituent constants. The reaction constant,—4.54, …

An extended table of Hammett substitutent constants based on the ionization of substituted benzoic acids

DH McDANIEL, HC Brown - The Journal of Organic Chemistry, 1958 - ACS Publications
It is recommended that a return be made to the use of the dissociation constants of substituted
benzoic acids as a basis for evaluating Hammett substituent constants. A survey of the …

A new technique for the conversion of olefins into organoboranes and related alcohols

HC Brown, BCS Rao - Journal of the American Chemical Society, 1956 - ACS Publications
(6) In a later run, the mp was 269-271.(7) The electrolyte assays on compounds Vila, b were
done by E. Rosenberg and RI Dorfman at the Worcester Foundation for Ex-perimental …

[BOOK][B] The nonclassical ion problem

HC Brown - 2012 - books.google.com
… I wish to thank Professor Brown, not only for the chance to comment on the chapters of
this book, but also for his hospitality during visits to Purdue University, where most of these …

New, highly active metal catalysts for the hydrolysis of borohydride

HC Brown, CA Brown - Journal of the American Chemical Society, 1962 - ACS Publications
was prepared according to McCormack. 1 An example of its use is the preparation of 4, 4'-di-nitrodiphenyl
carbodiimide, a hitherto unreported compound.^-Nitrophenyl isocyanate (21.0 …

[HTML][HTML] Safety and immunogenicity of seven COVID-19 vaccines as a third dose (booster) following two doses of ChAdOx1 nCov-19 or BNT162b2 in the UK (COV …

…, C Brown, K Naker, E Qureshi, C Trinham, C Sabine… - The Lancet, 2021 - thelancet.com
Background Few data exist on the comparative safety and immunogenicity of different
COVID-19 vaccines given as a third (booster) dose. To generate data to optimise selection of …

Enantiomeric Z-and E-crotyldiisopinocampheylboranes. Synthesis in high optical purity of all four possible stereoisomers of. beta.-methylhomoallyl alcohols

HC Brown, KS Bhat - Journal of the American Chemical Society, 1986 - ACS Publications
M= Li, Na, K, Mg, B, etc.^ units of both the erythro and three configurations constitute a
characteristically structural feature of numerous macrolide5 and polyether antibiotics. Regretably, …