Abstract
Research into organic field effect transistors (OFETs) has made significant advances—both scientifically and technologically—during the last decade, and the first products will soon enter the market. Printed electronic circuits using organic resistors, diodes and transistors may become cheap alternatives to silicon-based systems, especially in large-area applications. A key parameter for device operation, besides long term stability, is the reproducibility of the current–voltage behavior, which may be affected by hysteresis phenomena. Hysteresis effects are often observed in organic transistors during sweeps of the gate voltage (V GS). This hysteresis can originate in various ways, but comparative scientific investigations are rare and a comprehensive picture of “hysteresis phenomena” in OFETs is still missing. This review provides an overview of the physical effects that cause hysteresis and discusses the importance of such effects in OFETs in a comparative manner.
Graphical abstract













Similar content being viewed by others
References
Weimer PK (1962) Proc IRE 50:1462
Ebisawa F, Kurokawa T, Nara S (1983) J Appl Phys 54:3255
Kudo K, Yamashina M, Moriizumi T (1984) Jpn J Appl Phys 23:130
Tsumura A, Koezuka H, Ando T (1986) Appl Phys Lett 49:1210
Peng X, Horowitz G, Fichou D, Garnier F (1990) Appl Phys Lett 57:2013
Gelinck GH, Edzer H, Huitema A, van Veenendaal E, Cantatore E, Schrijnemakers L, van der Putten JB, Geuns TC, Beenhakkers M, Giesbers JB (2004) Nat Mater 3:106
Klauk H (ed) (2006) Organic electronics, materials, manufacturing and applications. Wiley-VCH, Weinheim
Hoppe A, Balster T, Muck T, Wagner V (2008) Phys Status Solidi A 205:612
PolyIC (2009) Pictures for the press. http://www.polyic.com/en/press-images.php. Accessed Feb 2009
Polymer Vision (2009) Product website. http://www.Polymervision.com. Accessed Feb 2009
Plastic Logic (2009) Website. http://www.plasticlogic.com. Accessed Feb 2009
Bao Z, Locklin J (eds) (2007) Organic field-effect transistors. CRC Press, Boca Raton
Salleo A (2007) Mater Today 10:38
Zaumseil J, Sirringhaus H (2007) Chem Rev 107:1296
Facchetti A (2007) Mater Today 10:28
Veres J, Ogier S, Lloyd G, de Leeuw D (2004) Chem Mater 16:4543
Facchetti A, Yoon MH, Marks TJ (2005) Adv Mater 17:1705
Singh TB, Sariciftci NS (2006) Annu Rev Mater Res 36:199
Torsi L, Farinola GM, Marinelli F, Tanese MC, Omar OH, Valli L, Babudri F, Palmisano F, Zambonini PG, Naso F (2008) Nat Mater 7:412
Someya T, Pal B, Huang J, Katz HE (2008) MRS Bull 33:690
Schroder DK (2006) Semiconductor material and device characterization. Wiley, New York
Fuller CS, Severiens JC (1954) Phys Rev 92:1322
Kessler JO, Tomkins BE, Blanc J (1963) Solid-State Electron 6:297
Snow EH, Grove AS, Deal BE, Sah CT (1965) J Appl Phys 36:1664
Young ND, Gill A (1992) Semicond Sci Technol 7:1103
Moll JL, Tarui Y (1963) IEEE T Electron Dev 10:338
Wu SY (1974) IEEE T Electron Dev 21:499
Würfel P, Batra IP (1973) Phys Rev B 8:5126
Batra IP, Würfel P, Silverman BD (1973) Phys Rev B 8:3257
Scott JF (2000) Ferroelectric memories. Springer, Berlin
Fujitsu (2009) Ferroelectric RAM. http://www.fujitsu.com/sg/services/micro/semiconductor/memory/fram/. Accessed Feb 2009
EE Times Asia (2009) Search results for “ferroelectric RAM.” http://www.eetasia.com/SEARCH/ART/ferroelectric+RAM.HTM. Accessed Feb 2009
Lustig N, Kanicki J (1989) J Appl Phys 65:3951
Leroux C, Mitard J, Ghibaudo G, Garros X, Reimbold G, Guillaumot B, Martin F (2004) IEDM Tech Dig 737–740
Fleetwood DM, Winokur PS, Reber RA, Meisenheimer TL, Schwank JR, Shaneyfelt MR, Riewe LC (1993) J Appl Phys 73:5058
Powell MJ (1989) IEEE T Electron Dev 36:2753
Gu G, Kane MG, Mau SC (2007) J Appl Phys 101:014504
Brown AR, Jarrett CP, de Leeuw DM, Matters M (1997) Synth Met 88:37
Mijalkovic S, Green D, Nejim A, Whiting G, Rankov A, Smith E, Halls J, Murphy C (2008) Modelling of organic field-effect transistors for technology and circuit design. In: Proc IEEE Int Conf Microelectron, Nis, Serbia, 11–14 May 2008, pp 469–476
Horowitz G, Hajlaoui R, Bourguiga R, Hajlaoui M (1999) Synth Met 101:401
Sze SM, Ng KK (2007) Physics of semiconductor devices. Wiley, Hoboken
Horowitz G, Hajlaoui R, Bouchriha H, Bourguiga R, Hajlaoui M (1998) Adv Mater 10:923
Mottaghi M, Horowitz G (2006) Org Electron 7:528
Horowitz G (1999) Physics of organic field-effect transistors (Chap. 14). In: Hadziioannou G, van Hutten PF (eds) Semiconducting polymer: chemistry, physics and engineering. Wiley-VCH, Weinheim
Lang DV, Chi X, Sergent AM, Ramirez AP (2003) Bias-dependent generation and quenching of defects in pentacene. http://arxiv.org/abs/cond-mat/0312721
Salleo A, Endicott F, Street RA (2005) Appl Phys Lett 86:263505
Knipp D, Street RA, Völkel A, Ho J (2003) J Appl Phys 93:347
Kane MG (2007) Organic thin-film transistors for flat-panel displays (Chap. 6.4). In: Bao Z, Locklin J (eds) Organic field-effect transistors. CRC Press, Boca Raton
Taylor DM (2006) IEEE T Dielect El In 13:1063
Salleo A, Street RA (2003) J Appl Phys 94:471
Andersson LM, Inganäs O (2007) Org Electron 8:423
Street RA (2008) Phys Rev B 77:165311
Rivera C, Munoz E (2009) Appl Phys Lett 94:053501
IEEE (2004) Standard 1620TM. In: IEEE standard test methods for the characterization of organic transistors and materials. IEEE, New York
Goldmann C, Haas S, Krellner C, Pernstich KP, Grundlach DJ, Batlogg B (2004) J Appl Phys 96:2080
Goldmann C, Krellner C, Pernstich KP, Haas S, Grundlach DJ, Batlogg B (2006) J Appl Phys 99:034507
Santato C, Capelli R, Loi MA, Murgia M, Cicoira F, Roy VAL, Stallinga P, Zamboni R, Rost C, Karg SF, Muccini M (2004) Synth Met 146:329
Petit C, Zander D, Lmimouni K, Ternisien M, Tondelier D, Lenfant S, Vuillaume D (2008) Org Electron 9:979
Noh YH, Park SY, Seo SM, Lee HH (2006) Org Electron 7:271
Yoon MH, Kim C, Facchetti A, Marks TJ (2006) J Am Chem Soc 128:12851
Stallinga P, Gomes HL, Biscarini F, Murgia M, de Leeuw DM (2004) J Appl Phys 96:5277
Hwang DK, Oh MS, Hwang JM, Kim JH, Im S (2008) Appl Phys Lett 92:013304
Schwödiauer R, Neugschandtner GS, Bauer-Gogonea S, Bauer S (1999) Appl Phys Lett 75:3998
Schmechel R, von Seggern H (2005) Electronic traps in organic transport layers. In: Brütting W (ed) Physics of organic semiconductors, Wiley-VCH, Weinheim, chap 10
Hwang DK, Lee K, Kim JH, Im S, Park JH, Kim E (2006) Appl Phys Lett 89:093507
Cayadi T, Tan HS, Namdas EB, Mhaisalkar SG, Lee PS, Chen ZK, Ng CM, Boey FYC (2007) Org Electron 8:455
Madec MB, Crouch D, Llorente GR, Whittle TJ, Geoghegan M, Yeates SG (2008) J Mater Chem 18:3230
Kitamura M, Kuzumoto Y, Kamura M, Aomori S, Arakawa Y (2007) Appl Phys Lett 91:183514
Kim W, Javey A, Vermesh O, Wang Q, Li Y, Dai H (2003) Nano Lett 3:193
Kim SH, Yang H, Yang SY, Hong K, Choi D, Yang C, Chung DS, Park CE (2008) Org Electron 9:673
Jung T, Dodabalapur A, Wenz R, Mohapatra S (2005) Appl Phys Lett 87:182109
Dinelli F, Murgia M, Biscarini F, de Leeuw DM (2004) Synth Met 146:373
Gu G, Kane MG (2008) Appl Phys Lett 92:053305
Zilker SJ, Detcheverry C, Cantatore E, de Leeuw DM (2001) Appl Phys Lett 79:1124
Mathijssen SGJ, Cölle M, Gomes H, Smits ECP, de Boer B, McCulloch I, Bobbert PA, de Leeuw DM (2007) Adv Mater 19:2785
Sekitani T, Iba S, Kato Y, Noguchi Y, Someya T, Sakurai T (2005) Appl Phys Lett 87:073505
Benor A, Knipp D, Northrup J, Völkel AR, Street RA (2008) J Non-Cryst Solids 354:2875
Gomes HL, Stallinga P, Cölle M, de Leeuw DM, Biscarini F (2006) Appl Phys Lett 88:082101
Chua LL, Zaumseil J, Chang JF, Ou ECW, Ho PKH, Sirringhaus H, Friend RH (2005) Nature 434:194
Lee S, Koo B, Shin J, Lee E, Park H, Kim H (2006) Appl Phys Lett 88:162109
Cai X, Gerlach CP, Frisbie CD (2007) J Phys Chem C 111:452
Ogawa S, Kimura Y, Niwano M, Ishii H (2007) Appl Phys Lett 90:33504
Kim WJ, Kim CS, Jo SJ, Lee SW, Lee SJ, Baik HK (2007) Electrochem Solid St 10:H1
Zhang XH, Domercq B, Kippelen B (2007) Appl Phys Lett 91:092114
Salleo A, Chabinyc ML, Yang MS, Street RA (2002) Appl Phys Lett 81:4383
Kim SC, Kim SH, Lee JH, Kim MK, Kim DJ, Zyung T (2005) Synth Met 148:75
Yagi I, Tsukagoshi K, Aoyagi Y (2005) Appl Phys Lett 86:103502
Zaumseil J, Friend RH, Sirringhaus H (2006) Nat Mater 5:69
Pal BN, Trottman P, Sun J, Katz HE (2008) Adv Funct Mater 18:1832
Marjanovic N (2005) Ph.D. thesis, Johannes Kepler University, Linz
Marjanovic N, Singh TB, Dennler G, Günes S, Neugebauer H, Sariciftci NS, Schwödiauer R, Bauer S (2006) Org Electron 7:188
Saragi TPI, Salbeck J (2006) Appl Phys Lett 89:253516
Veres J, Ogier SD, Leeming SW, Cupertino DC, Khaffaf SM (2003) Adv Funct Mater 13:199
Veres J, Ogier S, Leeming S, Cupertino D, Khaffaf SM, Lloyd G (2003) Proc SPIE 5217:147
Stassen AF, de Boer RWI, Iosad NN, Morpurgo AF (2004) Appl Phys Lett 85:3899
Zirkl M, Haase A, Fian A, Schön H, Sommer C, Jakopic G, Leising G, Stadlober B, Graz I, Gaar N, Schwödiauer R, Bauer-Gogonea S, Bauer S (2007) Adv Mater 19:2241
Stadlober B, Zirkl M, Beutl M, Leising G, Bauer-Gogonea S, Bauer S (2005) Appl Phys Lett 86:242902
Haas U, Gold H, Haase A, Jakopic G, Stadlober B (2007) Appl Phys Lett 91:043511
Irimia-Vladu M, Marjanovic N, Vlad A, Montaigne Ramil A, Hernandez-Soso G, Schwödiauer R, Bauer S, Sariciftci SN (2008) Adv Mater 20:3887
Scheinert S, Pernstich KP, Batlogg B, Paasch G (2007) J Appl Phys 102:104503
Lim E, Manaka T, Tamura R, Iwamoto M (2007) J Appl Phys 101:094505
Gu G, Kane MG, Doty JE, Firester AH (2005) Appl Phys Lett 87:243512
Siol C, Melzer C, von Seggern H (2008) Appl Phys Lett 93:133303
Ucurum C, Goebel H, Ylidimir FA, Bauhofer W, Krautschneider W (2008) J Appl Phys 104:084501
Ucurum C, Siemund H, Goebel H (2008) PSpice model for hysteresis in pentacene field-effect transistors. In: Proc 2nd IEEE Int Interdiscipl Conf on Portable Information Devices 2008; 2008 7th IEEE Conf on Polymers and Adhesives in Microelectronics and Photonics (PORTABLE-POLYTRONIC 2008), Garmisch-Partenkirchen, Germany, 17–20 Aug 2008, pp 1–3, ISBN 978-1-4244-2141-1
Liu Z, Xue F, Su Y, Lvov YM, Varahramyan K (2006) IEEE T Nanotechnol 5:379
Wu W, Zhang H, Wang Y, Ye S, Guo Y, Di C, Yu G, Zhu D, Liu Y (2008) Adv Funct Mater 18:2593
Mushrush M, Facchetti A, Lefenfeld M, Katz HE, Marks TJ (2003) J Am Chem Soc 125:9414
Facchetti A, Letizia J, Yoon MH, Mushrush M, Katz HE, Marks TJ (2004) Chem Mater 16:4715
Katz EH, Hong XM, Dodabalapur A, Sarpeshkar R (2002) J Appl Phys 91:1572
Baeg KJ, Noh YY, Ghim J, Kang SJ, Lee H, Kim DY (2006) Adv Mater 18:3179
Baeg KJ, Noh YY, Ghim J, Lim B, Kim DY (2008) Adv Funct Mater 18:3678
Ling QD, Liaw DJ, Zhu C, Chan DSH, Kang ET, Neoh KG (2008) Prog Polym Sci 33:917
Zhen L, Guan W, Shang L, Liu M, Liu G (2008) J Phys D Appl Phys 41:135111
Scheinert S, Paasch G, Pohlmann S, Hörhold HH, Stockmann R (2000) Solid State Electron 44:845
Scheinert S, Schliefke W (2003) Synth Met 139:501
Lindner T, Paasch G, Scheinert S (2005) J Appl Phys 98:114505
Swensen J, Kanicki J, Heeger AJ (2003) Proc SPIE Int Soc Opt Eng 5217:159
Pernstich KP, Haas S, Oberhoff D, Goldmann C, Gundlach DJ, Batlogg B, Rashid AN, Schitter G (2004) J Appl Phys 96:6431
Scheinert S, Paasch G (2004) Phys Stat Sol (a) 201:1263
Kirova N, Brazovskii S (1996) Synth Met 76:229
Salleo A, Street RA (2004) Phys Rev B 70:235324
Paasch G, Scheinert S, Herasimovich A, Hörselmann I, Lindner T (2008) Phys Status Solidi A 205:534
Paasch G (2004) Solid State Ionics 169:87
Paasch G, Scheinert S, Petr A, Dunsch L (2006) Russ J Electrochem 42:1161
Paasch G (2007) J Electroanal Chem 600:131
Street RA, Salleo A, Chabinyc ML (2003) Phys Rev B 68:085316
Vorotyntsev MA, Heinze J (2001) Electrochim Acta 46:3309
Bradley K, Cumings J, Star A, Gabriel JCP, Grunder G (2003) Nano Lett 3:639
Castriota M, Cazzanelli E, Nicotera I, Coppola IL, Oliviero C, Ranieri GA (2003) J Chem Phys 118:5537
Chintapalli S, Frech R (1996) Macromolecules 29:3499
Smits JHA, Meskers SCJ, Janssen RAJ, Marsman AW, de Leeuw DM (2005) Adv Mater 17:1169
Rep DBA, Morpurgo AF, Sloof WG, Klapwijk TM (2003) J Appl Phys 93:2082
Naber RCG (2006) Ph.D. thesis, University of Groningen, The Netherlands
Miller SL, McWhorter PJ (1992) J Appl Phys 72:5999
Naber RCG, Massolt J, Spijkman M, Asadi K, Blom PWM, de Leeuw DM (2007) Appl Phys Lett 90:113509
Velu G, Legrand C, Tharaud O, Chapoton A, Remiens D, Horowitz G (2001) Appl Phys Lett 79:659
Kodzasa T, Yoshida M, Uemura S, Kamata T (2003) Synth Met 137:943
Schroeder R, Majewski LA, Grell M (2004) Adv Mater 16:633
Schroeder R, Majewski LA, Voigt M, Grell M (2005) IEEE Electron Dev Lett 26:69
Unni KNN, de Bettignies R, Dabos-Seignon S, Nunzi JM (2004) Appl Phys Lett 85:1823
Naber RCG, Tanase C, Blom PWM, Gelinck GH, Marsman AW, Touwslager FJ, Setayesh S, de Leeuw DM (2005) Nat Mater 4:243
Naber RCG, Blom PWM, Gelinck GH, Marsman AW, de Leeuw DM (2005) Adv Mater 17:2692
Müller K, Paloumpa I, Henkel K, Schmeißler D (2006) Mater Sci Eng C 26:1028
Tamura R, Lim E, Yoshita S, Manaka T, Iwamoto M (2008) Thin Solid Films 516:2753
Mizuno E, Taniguchi M, Kawai T (2005) Appl Phys Lett 86:143513
Sekitani T, Nogitchi Y, Nakano S, Zaitsu K, Kato Y, Takamiya M, Sakurai T, Someya T (2007) Communication sheets using printed organic nonvolatile memories. In: Proc Electron Devices Meeting (IEDM 2007), San Francisco, CA, 10–12 Dec 2007, p 221
Park SY, Park M, Lee HH (2004) Appl Phys Lett 85:2283
Halik M (2006) Gate dielectrics (Chap. 6). In: Klauk H (ed) Organic electronics, materials, manufacturing and applications. Wiley-VCH, Weinheim
Lim SC, Kim SH, Koo JB, Lee JH, Ch Ku, Yang YS, Zyung T (2007) Appl Phys Lett 90:173512
Huang C, West JE, Katz HE (2007) Adv Funct Mater 17:142
Egginger M, Irimia-Vladu M, Schwödiauer R, Tanda A, Frischauf I, Bauer S, Sariciftci NS (2008) Adv Mater 20:1018
Uemura S, Yoshida M, Hoshino S, Kodzaza T, Kamata T (2003) Thin Solid Films 438–439:378
Horowitz G, Deloffre F, Garnier F, Hajlaoui R, Hmyene M, Yassar A (1993) Synth Met 54:435
Stadler P, Oppelt K, Singh TB, Grote JG, Schwödiauer R, Bauer S, Piglmayer-Brezina H, Bäuerle D, Sariciftci NS (2007) Org Electron 8:648
Singh B, Sariciftci NS, Grote JG, Hopkins FK (2006) J Appl Phys 100:024514
Ng TN, Daniel JH, Sambandan S, Arias AC, Chabinyc ML, Street RA (2008) J Appl Phys 103:044506
Panzer MJ, Newman CR, Frisbie CD (2005) Appl Phys Lett 86:103503
Singh TB, Marjanovic N, Matt GJ, Sariciftci NS, Schwödiauer R, Bauer S (2004) Appl Phys Lett 85:5409
Singh TB, Marjanovic N, Sariciftci NS, Schwödiauer R, Bauer S (2006) IEEE T Dielect El In 13:1082
Singh TB, Marjanovic N, Stadler P, Auinger M, Matt GJ, Günes S, Sariciftci NS, Schwödiauer R, Bauer S (2005) J Appl Phys 97:083714
Singh TB, Meghdadi F, Günes S, Marjanovic N, Horowitz G, Lang P, Bauer S, Sariciftci NS (2005) Adv Mater 17:2315
Coelho R (1991) J Non-Cryst Solids 131:1136
Klein RJ, Zhang S, Dou S, Jones BH, Colby RH, Runt J (2006) J Chem Phys 124:144903
Frübing P, Wegener M, Gerhard-Multhaupt R, Buchsteiner A, Neumann W, Brehmer L (1999) Polymer 40:3413
Wegener M (2001) IEEE T Dielect El In 8:494
Kremer F, Schönhals A (2003) Analysis of dielectric spectra. In: Kremer F, Schönhals A (eds) Broadband dielectric spectroscopy. Springer, Berlin, pp 87–93
Mauritz KA (1989) Macromolecules 22:4483
Martin B, Kliem H (2005) J Appl Phys 98:74102
Edman L, Swensen J, Moses D, Heeger AJ (2004) Appl Phys Lett 84:3744
Bernards DA, Flores-Torres S, Abruna HD, Malliaras GG (2006) Science 313:1416
Waser R, Aono M (2007) Nat Mater 6:833
Cayadi T, Tan HS, Mhaisalkar SG, Lee PS, Boey FYC, Chen ZK, Ng CM, Rao VR, Qi GJ (2007) Appl Phys Lett 91:242107
Lee CA, Park DW, Jin SH, Park IH, Lee JD, Park BG (2006) Appl Phys Lett 88:252102
Lee CA, Park DW, Jung KD, Kim BJ, Kim YC, Lee JD, Park BG (2006) Appl Phys Lett 89:262120
Kolliopoulou S, Dimitrakis P, Normand P, Zhang HL, Cant N, Evans SD, Paul S, Pearson C, Molloy A, Petty MC, Tsoukalas D (2003) J Appl Phys 94:5234
Kolliopoulou S, Dimitrakis P, Normand P, Zhang HL, Cant N, Evans SD, Paul S, Pearson C, Molloy A, Petty MC, Tsoukalas D (2004) Microelectron Eng 73–74:725
Kitamura M, Arakawa Y (2007) Appl Phys Lett 91:053505
Horie M, Luo Y, Morrison JJ, Majewski LA, Song A, Saunders BR, Turner ML (2008) J Mater Chem 18:5230
Park DW, Lee CA, Jung KD, Park BG, Shin H, Lee JD (2006) Appl Phys Lett 89:263507
Scott JC, Bozano LD (2007) Adv Mater 19:1452
Acknowledgments
M.E. is grateful to Philipp Stadler (LIOS) and Robert Koeppe (http://www.isiQiri.com) for fruitful discussions. This work was performed within FWF project P20772-N20 of the Austrian Science Fund (FWF) National Research Network (NFN S9711), and COST action D35 as part of European Cooperation in the Field of Scientific and Technical Research.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Egginger, M., Bauer, S., Schwödiauer, R. et al. Current versus gate voltage hysteresis in organic field effect transistors. Monatsh Chem 140, 735–750 (2009). https://doi.org/10.1007/s00706-009-0149-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00706-009-0149-z